Time-Resolved Fluorescence of Ferrocene/Flavin/Viologen/TCNQ Hetero LB Film

Kyung Sang Cho; Jeong Woo Choi; Won Hong Lee; Nam Woong Song; Dongho Kim

doi:10.1080/10587259908026824

Time-Resolved Fluorescence of Ferrocene/Flavin/Viologen/TCNQ Hetero LB Film

Kyung Sang Cho, Jeong Woo Choi, Won Hong Lee, Nam Woong Song, Dongho Kim

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Time-resolved fluorescence was measured with hetero Langmuir-Blodgett (LB) films consisting of ferrocene/flavin/viologen/TCNQ on quartz substrate. Ferrocene, flavin, viologen and TCNQ were used as a electron donor (D), sensitizer (S), relay (R) and acceptor (A) units, respectively. Power dependence on charge separation rate was investigated to examine the local heating problem or the excited state annihilation. Based on the decay of fluorescence, charge separation from excited S to R (or A) was calculated. Result showed that long-range electron transfer from S to A occurred in the D/S/R/A hetero LB film in addition to the electron transfer from S to R.

Original language	English
Pages (from-to)	245-248
Number of pages	4
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	327
DOIs	https://doi.org/10.1080/10587259908026824
Publication status	Published - 1999

Bibliographical note

Funding Information:
This work is supported by the Research Fund on Optical Technology (F-15, 1997) of Korean Ministry of Science and Technology and supported by Creative Research Initiatives of the Korean Ministry of Science and Technology.

All Science Journal Classification (ASJC) codes

Condensed Matter Physics

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10.1080/10587259908026824

Cite this

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title = "Time-Resolved Fluorescence of Ferrocene/Flavin/Viologen/TCNQ Hetero LB Film",

abstract = "Time-resolved fluorescence was measured with hetero Langmuir-Blodgett (LB) films consisting of ferrocene/flavin/viologen/TCNQ on quartz substrate. Ferrocene, flavin, viologen and TCNQ were used as a electron donor (D), sensitizer (S), relay (R) and acceptor (A) units, respectively. Power dependence on charge separation rate was investigated to examine the local heating problem or the excited state annihilation. Based on the decay of fluorescence, charge separation from excited S to R (or A) was calculated. Result showed that long-range electron transfer from S to A occurred in the D/S/R/A hetero LB film in addition to the electron transfer from S to R.",

author = "Cho, {Kyung Sang} and Choi, {Jeong Woo} and Lee, {Won Hong} and Song, {Nam Woong} and Dongho Kim",

note = "Funding Information: This work is supported by the Research Fund on Optical Technology (F-15, 1997) of Korean Ministry of Science and Technology and supported by Creative Research Initiatives of the Korean Ministry of Science and Technology.",

year = "1999",

doi = "10.1080/10587259908026824",

language = "English",

volume = "327",

pages = "245--248",

journal = "Molecular Crystals and Liquid Crystals",

issn = "1542-1406",

publisher = "Taylor and Francis Ltd.",

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T1 - Time-Resolved Fluorescence of Ferrocene/Flavin/Viologen/TCNQ Hetero LB Film

AU - Cho, Kyung Sang

AU - Choi, Jeong Woo

AU - Lee, Won Hong

AU - Song, Nam Woong

AU - Kim, Dongho

N1 - Funding Information: This work is supported by the Research Fund on Optical Technology (F-15, 1997) of Korean Ministry of Science and Technology and supported by Creative Research Initiatives of the Korean Ministry of Science and Technology.

PY - 1999

Y1 - 1999

N2 - Time-resolved fluorescence was measured with hetero Langmuir-Blodgett (LB) films consisting of ferrocene/flavin/viologen/TCNQ on quartz substrate. Ferrocene, flavin, viologen and TCNQ were used as a electron donor (D), sensitizer (S), relay (R) and acceptor (A) units, respectively. Power dependence on charge separation rate was investigated to examine the local heating problem or the excited state annihilation. Based on the decay of fluorescence, charge separation from excited S to R (or A) was calculated. Result showed that long-range electron transfer from S to A occurred in the D/S/R/A hetero LB film in addition to the electron transfer from S to R.

AB - Time-resolved fluorescence was measured with hetero Langmuir-Blodgett (LB) films consisting of ferrocene/flavin/viologen/TCNQ on quartz substrate. Ferrocene, flavin, viologen and TCNQ were used as a electron donor (D), sensitizer (S), relay (R) and acceptor (A) units, respectively. Power dependence on charge separation rate was investigated to examine the local heating problem or the excited state annihilation. Based on the decay of fluorescence, charge separation from excited S to R (or A) was calculated. Result showed that long-range electron transfer from S to A occurred in the D/S/R/A hetero LB film in addition to the electron transfer from S to R.

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JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

ER -

Time-Resolved Fluorescence of Ferrocene/Flavin/Viologen/TCNQ Hetero LB Film

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

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