Toward the rational design of supramolecular coordination polymers. The effect of solvent and substituent changes on the structure of self-assembled metal-organometallic networks

Moonhyun Oh, Gene B. Carpenter, D. A. Sweigart

Research output: Contribution to journalArticle

47 Citations (Scopus)

Abstract

Self-assembly of the π-complex (η4-benzoquinone)Mn(CO)3- (QMTC) with metal ions [Mn(II), Co(II), Zn(II)] generates neutral metal-organometallic coordination networks (MOMNs). The network architecture can be controlled by (1) a solvent-induced change in coordination geometry at the metal nodes and (2) the introduction of substituents on the benzoquinone ring.

Original languageEnglish
Pages (from-to)2364-2366
Number of pages3
JournalOrganometallics
Volume22
Issue number12
DOIs
Publication statusPublished - 2003 Jun 9

Fingerprint

quinones
Organometallics
coordination polymers
Polymers
Metals
Carbon Monoxide
Network architecture
metals
Self assembly
Metal ions
self assembly
metal ions
Geometry
rings
geometry
benzoquinone

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

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Toward the rational design of supramolecular coordination polymers. The effect of solvent and substituent changes on the structure of self-assembled metal-organometallic networks. / Oh, Moonhyun; Carpenter, Gene B.; Sweigart, D. A.

In: Organometallics, Vol. 22, No. 12, 09.06.2003, p. 2364-2366.

Research output: Contribution to journalArticle

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