Toward the rational design of supramolecular coordination polymers. The effect of solvent and substituent changes on the structure of self-assembled metal-organometallic networks

Moonhyun Oh, Gene B. Carpenter, D. A. Sweigart

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Abstract

Self-assembly of the π-complex (η4-benzoquinone)Mn(CO)3- (QMTC) with metal ions [Mn(II), Co(II), Zn(II)] generates neutral metal-organometallic coordination networks (MOMNs). The network architecture can be controlled by (1) a solvent-induced change in coordination geometry at the metal nodes and (2) the introduction of substituents on the benzoquinone ring.

Original languageEnglish
Pages (from-to)2364-2366
Number of pages3
JournalOrganometallics
Volume22
Issue number12
DOIs
Publication statusPublished - 2003 Jun 9

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All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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