Transient permeation of binary and ternary gas mixtures on mtes templating silica/á-alumina composite membrane

Jong Ho Moon, Sang Jin Lee, Sang Hoon Hyun, Chang Ha Lee

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

The equilibirum and kinetic characteristics of a MTES (methyltriethoxysilane) templating silica/α-alumina composite membrane were studied using unsteady and steady-state permeation of pure CO2, N2, CH4, H2, and He gases. The saturated amount of adsorption, Langmuir parameter, and diffusivity could be estimated by the generalized Maxwell-Stefan model, the incorporating dust gas model, and the Langmuir model using transient and steady-state measurements. The experimental and theoretical studies were extended to multicomponent gas mixture separation from single gas permeation. Since the permeation flux in the MTES membrane was affected by molecular sieving effects as well as surface diffusion properties, the kinetic and equilibrium separation should be considered simultaneously in the membrane according to molecular properties. All mathematical simulations and parameter estimations were performed by gPROMS dynamic simulator. This is an abstract of a paper presented at the 2006 AIChE National Meeting (San Francisco, CA 11/12-17/2006).

Original languageEnglish
Title of host publication2006 AIChE Annual Meeting
Publication statusPublished - 2006 Dec 1
Event2006 AIChE Annual Meeting - San Francisco, CA, United States
Duration: 2006 Nov 122006 Nov 17

Publication series

NameAIChE Annual Meeting, Conference Proceedings

Other

Other2006 AIChE Annual Meeting
CountryUnited States
CitySan Francisco, CA
Period06/11/1206/11/17

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All Science Journal Classification (ASJC) codes

  • Biotechnology
  • Chemical Engineering(all)
  • Bioengineering
  • Safety, Risk, Reliability and Quality

Cite this

Moon, J. H., Lee, S. J., Hyun, S. H., & Lee, C. H. (2006). Transient permeation of binary and ternary gas mixtures on mtes templating silica/á-alumina composite membrane. In 2006 AIChE Annual Meeting (AIChE Annual Meeting, Conference Proceedings).