Transient X-ray diffraction reveals global and major reaction pathways for the photolysis of iodoform in solution

Jae Hyuk Lee, Joonghan Kim, Marco Cammarata, Qingyu Kong, Kyung Hwan Kim, Jungkweon Choi, Tae Kyu Kim, Michael Wulff, Hyotcherl Ihee

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

(Figure Presented) The structural dynamics of the photodissociation of iodoform in methanol (see picture: H blue, C green, I violet) are revealed by means of time-resolved X-ray diffraction in solution (also called transient X-ray liquidography because of its analogy to crystallography). While spectroscopic studies suggest the existence of isoiodoform, no signals are observed for this intermediate species in time-resolved diffraction experiments performed using time delays between 100 ps and 3 μs.

Original languageEnglish
Pages (from-to)1047-1050
Number of pages4
JournalAngewandte Chemie - International Edition
Volume47
Issue number6
DOIs
Publication statusPublished - 2008 Feb 11

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Photodissociation
Crystallography
Structural dynamics
Photolysis
Methanol
Time delay
Diffraction
X ray diffraction
X rays
Experiments
iodoform

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Lee, Jae Hyuk ; Kim, Joonghan ; Cammarata, Marco ; Kong, Qingyu ; Kim, Kyung Hwan ; Choi, Jungkweon ; Kim, Tae Kyu ; Wulff, Michael ; Ihee, Hyotcherl. / Transient X-ray diffraction reveals global and major reaction pathways for the photolysis of iodoform in solution. In: Angewandte Chemie - International Edition. 2008 ; Vol. 47, No. 6. pp. 1047-1050.
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Transient X-ray diffraction reveals global and major reaction pathways for the photolysis of iodoform in solution. / Lee, Jae Hyuk; Kim, Joonghan; Cammarata, Marco; Kong, Qingyu; Kim, Kyung Hwan; Choi, Jungkweon; Kim, Tae Kyu; Wulff, Michael; Ihee, Hyotcherl.

In: Angewandte Chemie - International Edition, Vol. 47, No. 6, 11.02.2008, p. 1047-1050.

Research output: Contribution to journalArticle

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