Tris(trimethylsilyl)silane and diphenylsilane in the radical chain dideoxygenation of 1,6-anhydro-D-glucose: A comparative study

Derek H.R. Barton, Doook Jang, Joseph Cs Jaszberenyi

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

The 2,4-bis-thinocarbonate 3 of 1,6-anyhydro-D-glucose 1 can be transformed to the corresponding dideoxy compound 5 with diphenylsilane 7 as well as with tris(trimethylsilyl)silane 4 in a radical chain reaction.

Original languageEnglish
Pages (from-to)6629-6632
Number of pages4
JournalTetrahedron Letters
Volume33
Issue number44
DOIs
Publication statusPublished - 1992 Oct 27

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Silanes
Glucose

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

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abstract = "The 2,4-bis-thinocarbonate 3 of 1,6-anyhydro-D-glucose 1 can be transformed to the corresponding dideoxy compound 5 with diphenylsilane 7 as well as with tris(trimethylsilyl)silane 4 in a radical chain reaction.",
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Tris(trimethylsilyl)silane and diphenylsilane in the radical chain dideoxygenation of 1,6-anhydro-D-glucose : A comparative study. / Barton, Derek H.R.; Jang, Doook; Jaszberenyi, Joseph Cs.

In: Tetrahedron Letters, Vol. 33, No. 44, 27.10.1992, p. 6629-6632.

Research output: Contribution to journalArticle

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AU - Barton, Derek H.R.

AU - Jang, Doook

AU - Jaszberenyi, Joseph Cs

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AB - The 2,4-bis-thinocarbonate 3 of 1,6-anyhydro-D-glucose 1 can be transformed to the corresponding dideoxy compound 5 with diphenylsilane 7 as well as with tris(trimethylsilyl)silane 4 in a radical chain reaction.

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