Tunable pore size and porosity of spherical polyimide aerogel by introducing swelling method based on spherulitic formation mechanism

Daero Lee, Jinyoung Kim, Seohyun Kim, Gunhwi Kim, Jihun Roh, Sangrae Lee, Haksoo Han

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14 Citations (Scopus)


In this study, the swelling method for controlling the pore size of the polyimide aerogel is demonstrated. The swelling method allows the pore size to be increased by changing the spherulitic formation. This newly developed method is simple and hardly affects original polymer chain and thus can be applied to a variety of precursor polymers without hindering the synthesis process. Unlike other methods, no foreign additives such as additional chemicals or crosslinkers are required to enlarge the pores of the aerogel, which contributes to higher homogeneity of the material. In order to test its effectiveness in pore size control and observe its behavior with different polyimides, various monomers—pyromellitic dianhydride, 3,3′,4,4′-benzophenonete-trac-arboxylic dianhydride, and 4,4′-oxydiphthalic anhydride—were tested to verify the potential of the proposed method. Depending on different polymer backbone, each aerogel showed a similar slope but different increase rate of the pore size. The retained thermal and structural properties of the synthesized aerogels were confirmed by thermogravimetric analysis, differential scanning calorimetry, and Fourier-transform infrared spectroscopy. This newly proposed simple method showed its effectiveness in increasing the pore sizes, enlarging the mesopore size from 4 nm to 20 nm and total pore volume from 1.29 cm3/g to 2.06 cm3/g for swollen aerogel when pyromellitic dianhydride was used. Also, the surface area increased from 54 m2/g to 88 m2/g, and the porosity increased from 58% to 73%.

Original languageEnglish
Article number109546
JournalMicroporous and Mesoporous Materials
Publication statusPublished - 2019 Nov 1

Bibliographical note

Funding Information:
This work was supported by a National Research Foundation of Korea grant funded by the Korean government (MSIT) ( No. 2017R1D1A1B03033332 ), the Commercialization Promotion Agency for R&D Outcomes (COMPA) funded by the Ministry of Science and ICT (MSIT) (No. 2019K000072 ) and the Human Resources Program in Energy Technology of the Korea Institute of Energy Technology Evaluation and Planning , which was granted financial resources from the Ministry of Trade, Industry & Energy, Republic of Korea (No. 20174010201640 ).

Publisher Copyright:
© 2019 Elsevier Inc.

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials


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