Twist boat conformation of thiane S-oxide both in solid state and in solution

Ju Jeon Dong; Ikyon Kim

doi:10.5012/bkcs.2008.29.7.1369

Twist boat conformation of thiane S-oxide both in solid state and in solution

Ju Jeon Dong, Ikyon Kim

Department of Pharmacy

Research output: Contribution to journal › Article › peer-review

Abstract

A stable twist boat conformation of thiane S-oxide 1a in solid state and in solution was unambiguously determined by single crystal X-ray crystallography and solution NMR analyses. On the contrary, the thiane Sdioxide 2 which was obtained from the oxidation of corresponding thiane S-oxide 1a was confirmed to adopt a regular chair conformation.

Original language	English
Pages (from-to)	1369-1373
Number of pages	5
Journal	Bulletin of the Korean Chemical Society
Volume	29
Issue number	7
DOIs	https://doi.org/10.5012/bkcs.2008.29.7.1369
Publication status	Published - 2008 Jul 20

All Science Journal Classification (ASJC) codes

Chemistry(all)

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abstract = "A stable twist boat conformation of thiane S-oxide 1a in solid state and in solution was unambiguously determined by single crystal X-ray crystallography and solution NMR analyses. On the contrary, the thiane Sdioxide 2 which was obtained from the oxidation of corresponding thiane S-oxide 1a was confirmed to adopt a regular chair conformation.",

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AU - Kim, Ikyon

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AB - A stable twist boat conformation of thiane S-oxide 1a in solid state and in solution was unambiguously determined by single crystal X-ray crystallography and solution NMR analyses. On the contrary, the thiane Sdioxide 2 which was obtained from the oxidation of corresponding thiane S-oxide 1a was confirmed to adopt a regular chair conformation.

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