Two-Dimensional Materials on the Rocks: Positive and Negative Role of Dopants and Impurities in Electrochemistry

Shu Min Tan, Martin Pumera

Research output: Contribution to journalReview article

12 Citations (Scopus)

Abstract

Two-dimensional (2D) materials, such as graphene and transition-metal chalcogenides, were shown in many works as very potent catalysts for industrially important electrochemical reactions, such as oxygen reduction, hydrogen and oxygen evolution, and carbon dioxide reduction. We critically discuss here the development in the field, showing that not only dopants but also impurities can have dramatic effects on catalysis. Note here that the difference between dopant and impurity is merely semantic-dopant is an impurity deliberately added to the material. We contest the general belief that all doping has a positive effect on electrocatalysis. We show that in many cases, dopants actually inhibit the electrochemistry of 2D materials. This review provides a balanced view of the field of 2D materials electrocatalysis.

Original languageEnglish
Pages (from-to)2681-2728
Number of pages48
JournalACS Nano
Volume13
Issue number3
DOIs
Publication statusPublished - 2019 Mar 26

Fingerprint

Electrochemistry
electrochemistry
Rocks
Doping (additives)
rocks
Impurities
impurities
Electrocatalysis
semantics
chalcogenides
oxygen
catalysis
carbon dioxide
Oxygen
graphene
Chalcogenides
transition metals
Graphite
catalysts
Carbon Dioxide

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

Cite this

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abstract = "Two-dimensional (2D) materials, such as graphene and transition-metal chalcogenides, were shown in many works as very potent catalysts for industrially important electrochemical reactions, such as oxygen reduction, hydrogen and oxygen evolution, and carbon dioxide reduction. We critically discuss here the development in the field, showing that not only dopants but also impurities can have dramatic effects on catalysis. Note here that the difference between dopant and impurity is merely semantic-dopant is an impurity deliberately added to the material. We contest the general belief that all doping has a positive effect on electrocatalysis. We show that in many cases, dopants actually inhibit the electrochemistry of 2D materials. This review provides a balanced view of the field of 2D materials electrocatalysis.",
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Two-Dimensional Materials on the Rocks : Positive and Negative Role of Dopants and Impurities in Electrochemistry. / Tan, Shu Min; Pumera, Martin.

In: ACS Nano, Vol. 13, No. 3, 26.03.2019, p. 2681-2728.

Research output: Contribution to journalReview article

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AU - Pumera, Martin

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