Ultra-fast shock-wave combustion synthesis of nanostructured silicon from sand with excellent Li storage performance

Ali Reza Kamali, Safa Haghighat-Shishavan, Masoud Nazarian-Samani, Asma Rezaei, Kwang Bum Kim

Research output: Contribution to journalArticle

Abstract

The available technologies used for the preparation of elemental silicon (Si), including the traditional carbothermal technology of producing bulk Si, pyrolysis-based methods of producing Si nanoparticles and the metallothermic fabrication of state-of-the-art nanostructured Si powder are all considered energy- and time-intensive processes, with associated environmental issues. Herein, for the first time, a combustion synthesis methodology, involving the occurrence of an ignition event followed by the immediate completion of the process, is used for the preparation of nanostructured Si for energy applications. In this process, Si powders are directly extracted from sea sand by a novel ultra-fast shock-wave combustion synthesis (SWCS), in which KClO4 is employed as the combustion agent to promote the immediate reduction of SiO2. The reaction is completed at an ignition temperature of about 550 °C, requiring virtually no dwell time. The process is scalable, green and carbon-free with a low energy consumption of about 100 kW h per ton, less than one percent of that of the current technologies. The Si product possesses a nanostructured mesoporous integrated sheet-like (NMIS) morphology, with an excellent and stable Li storage performance. The mechanism involved in the proposed method is also discussed. The feasibility of the SWCS approach for the preparation of Si is demonstrated in this article, based on which a variety of nanostructured materials is expected to be produced by this method.

Original languageEnglish
Pages (from-to)1396-1405
Number of pages10
JournalSustainable Energy and Fuels
Volume3
Issue number6
DOIs
Publication statusPublished - 2019 Jan 1

Fingerprint

Combustion synthesis
Shock waves
Sand
Silicon
Ignition
Powders
Nanostructured materials
Pyrolysis
Energy utilization
Nanoparticles
Fabrication
Carbon

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Energy Engineering and Power Technology

Cite this

Kamali, Ali Reza ; Haghighat-Shishavan, Safa ; Nazarian-Samani, Masoud ; Rezaei, Asma ; Kim, Kwang Bum. / Ultra-fast shock-wave combustion synthesis of nanostructured silicon from sand with excellent Li storage performance. In: Sustainable Energy and Fuels. 2019 ; Vol. 3, No. 6. pp. 1396-1405.
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Ultra-fast shock-wave combustion synthesis of nanostructured silicon from sand with excellent Li storage performance. / Kamali, Ali Reza; Haghighat-Shishavan, Safa; Nazarian-Samani, Masoud; Rezaei, Asma; Kim, Kwang Bum.

In: Sustainable Energy and Fuels, Vol. 3, No. 6, 01.01.2019, p. 1396-1405.

Research output: Contribution to journalArticle

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