Ultra-selective ferric ion-complexed membranes composed of water-based zwitterionic comb copolymers

Min Su Park, Na Un Kim, Byeong Ju Park, Du Yeol Ryu, Jong Hak Kim

Research output: Contribution to journalArticle

Abstract

Water-based, non-toxic, eco-friendly polymerization is carried out to synthesize a zwitterionic comb copolymer, i.e., poly(oxyethylene methacrylate)-co-sulfobetaine methacrylate (POEM-PSBMA). POEM-PSBMA undergoes a specific interaction with ferric (Fe3+) ions to form a three-dimensional, interconnected transporting channel for CO2. Without any post-treatment, the as-synthesized POEM-PSBMA solution complexed with ferric ions is directly coated onto a microporous polysulfone support to form thin-film composite membranes. The chain morphology and structure are determined by employing Fourier transform infrared spectroscopy (FT-IR), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), small angle X-ray scattering (SAXS), and energy-filtered transmission electron microscopy (EF-TEM). Microphase-separated structures are observed for all membranes, and the structures become smaller with increasing ferric ion loadings. This results from the selective interaction between ferric ions and POEM chains in the copolymer, leading to an increased number of CO2-philic sites. The coordination of the ferric ions reduces the free volume in the polymer matrix and hinders the diffusion of non-polar gases such as CH4 and N2. As a result, the CO2/N2 ideal selectivity and CO2/CH4 mixture selectivity are dramatically enhanced from 4.01 and 8.26 to 423 and 695, respectively, which represent the highest performances reported so far, to our knowledge.

Original languageEnglish
Pages (from-to)20847-20853
Number of pages7
JournalJournal of Materials Chemistry A
Volume7
Issue number36
DOIs
Publication statusPublished - 2019 Jan 1

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Copolymers
Ions
Membranes
Water
Methacrylates
Polysulfones
Composite membranes
Free volume
X ray scattering
Polymer matrix
Fourier transform infrared spectroscopy
Thermogravimetric analysis
Differential scanning calorimetry
Gases
Polymerization
Transmission electron microscopy
Thin films

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

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title = "Ultra-selective ferric ion-complexed membranes composed of water-based zwitterionic comb copolymers",
abstract = "Water-based, non-toxic, eco-friendly polymerization is carried out to synthesize a zwitterionic comb copolymer, i.e., poly(oxyethylene methacrylate)-co-sulfobetaine methacrylate (POEM-PSBMA). POEM-PSBMA undergoes a specific interaction with ferric (Fe3+) ions to form a three-dimensional, interconnected transporting channel for CO2. Without any post-treatment, the as-synthesized POEM-PSBMA solution complexed with ferric ions is directly coated onto a microporous polysulfone support to form thin-film composite membranes. The chain morphology and structure are determined by employing Fourier transform infrared spectroscopy (FT-IR), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), small angle X-ray scattering (SAXS), and energy-filtered transmission electron microscopy (EF-TEM). Microphase-separated structures are observed for all membranes, and the structures become smaller with increasing ferric ion loadings. This results from the selective interaction between ferric ions and POEM chains in the copolymer, leading to an increased number of CO2-philic sites. The coordination of the ferric ions reduces the free volume in the polymer matrix and hinders the diffusion of non-polar gases such as CH4 and N2. As a result, the CO2/N2 ideal selectivity and CO2/CH4 mixture selectivity are dramatically enhanced from 4.01 and 8.26 to 423 and 695, respectively, which represent the highest performances reported so far, to our knowledge.",
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Ultra-selective ferric ion-complexed membranes composed of water-based zwitterionic comb copolymers. / Park, Min Su; Kim, Na Un; Park, Byeong Ju; Ryu, Du Yeol; Kim, Jong Hak.

In: Journal of Materials Chemistry A, Vol. 7, No. 36, 01.01.2019, p. 20847-20853.

Research output: Contribution to journalArticle

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T1 - Ultra-selective ferric ion-complexed membranes composed of water-based zwitterionic comb copolymers

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AU - Kim, Na Un

AU - Park, Byeong Ju

AU - Ryu, Du Yeol

AU - Kim, Jong Hak

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