Ultrafast Flame Annealing of TiO2 Paste for Fabricating Dye-Sensitized and Perovskite Solar Cells with Enhanced Efficiency

Jung Kyu Kim, Sung Uk Chai, Yoonjun Cho, Lili Cai, Sung June Kim, Sangwook Park, Jong Hyeok Park, Xiaolin Zheng

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Mesoporous TiO2 nanoparticle (NP) films are broadly used as electrodes in photoelectrochemical cells, dye-sensitized solar cells (DSSCs), and perovskite solar cells (PSCs). State-of-the-art mesoporous TiO2 NP films for these solar cells are fabricated by annealing TiO2 paste-coated fluorine-doped tin oxide glass in a box furnace at 500 °C for ≈30 min. Here, the use of a nontraditional reactor, i.e., flame, is reported for the high throughput and ultrafast annealing of TiO2 paste (≈1 min). This flame-annealing method, compared to conventional furnace annealing, exhibits three distinct benefits. First, flame removes polymeric binders in the initial TiO2 paste more completely because of its high temperature (≈1000 °C). Second, flame induces strong interconnections between TiO2 nanoparticles without affecting the underlying transparent conducting oxide substrate. Third, the flame-induced carbothermic reduction on the TiO2 surface facilitates charge injection from the dye/perovskite to TiO2. Consequently, when the flame-annealed mesoporous TiO2 film is used to fabricate DSSCs and PSCs, both exhibit enhanced charge transport and higher power conversion efficiencies than those fabricated using furnace-annealed TiO2 films. Finally, when the ultrafast flame-annealing method is combined with a fast dye-coating method to fabricate DSSC devices, its total fabrication time is reduced from over 3 h to ≈10 min.

Original languageEnglish
Article number1702260
JournalSmall
Volume13
Issue number42
DOIs
Publication statusPublished - 2017 Nov 13

All Science Journal Classification (ASJC) codes

  • Biotechnology
  • Biomaterials
  • Chemistry(all)
  • Materials Science(all)

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