Ultrafast soft X-ray spectroscopy of spin-crossover dynamics in solvated transition-metal complexes

N. Huse, H. N. Cho, T. K. Kim, L. Jamula, J. K. McCusker, R. W. Schoenlein

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

We report the first femtosecond time-resolved soft x-ray measurements of solvated transition-metal complexes. L-edge spectroscopy directly reveals dynamic changes in ligand field splitting of 3d-orbitals associated with the spin transition, and mediated by ligand-bond changes.

Original languageEnglish
Title of host publicationLaser Science, LS 2009
PublisherOptical Society of America
ISBN (Print)9781557528780
Publication statusPublished - 2009 Jan 1
EventLaser Science, LS 2009 - San Jose, CA, United States
Duration: 2009 Oct 112009 Oct 15

Publication series

NameOptics InfoBase Conference Papers
ISSN (Electronic)2162-2701

Other

OtherLaser Science, LS 2009
CountryUnited States
CitySan Jose, CA
Period09/10/1109/10/15

Fingerprint

Spin dynamics
Metal complexes
X ray spectroscopy
Transition metals
crossovers
transition metals
Ligands
ligands
spectroscopy
x rays
Spectroscopy
X rays
orbitals

All Science Journal Classification (ASJC) codes

  • Instrumentation
  • Atomic and Molecular Physics, and Optics

Cite this

Huse, N., Cho, H. N., Kim, T. K., Jamula, L., McCusker, J. K., & Schoenlein, R. W. (2009). Ultrafast soft X-ray spectroscopy of spin-crossover dynamics in solvated transition-metal complexes. In Laser Science, LS 2009 (Optics InfoBase Conference Papers). Optical Society of America.
Huse, N. ; Cho, H. N. ; Kim, T. K. ; Jamula, L. ; McCusker, J. K. ; Schoenlein, R. W. / Ultrafast soft X-ray spectroscopy of spin-crossover dynamics in solvated transition-metal complexes. Laser Science, LS 2009. Optical Society of America, 2009. (Optics InfoBase Conference Papers).
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Huse, N, Cho, HN, Kim, TK, Jamula, L, McCusker, JK & Schoenlein, RW 2009, Ultrafast soft X-ray spectroscopy of spin-crossover dynamics in solvated transition-metal complexes. in Laser Science, LS 2009. Optics InfoBase Conference Papers, Optical Society of America, Laser Science, LS 2009, San Jose, CA, United States, 09/10/11.

Ultrafast soft X-ray spectroscopy of spin-crossover dynamics in solvated transition-metal complexes. / Huse, N.; Cho, H. N.; Kim, T. K.; Jamula, L.; McCusker, J. K.; Schoenlein, R. W.

Laser Science, LS 2009. Optical Society of America, 2009. (Optics InfoBase Conference Papers).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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Huse N, Cho HN, Kim TK, Jamula L, McCusker JK, Schoenlein RW. Ultrafast soft X-ray spectroscopy of spin-crossover dynamics in solvated transition-metal complexes. In Laser Science, LS 2009. Optical Society of America. 2009. (Optics InfoBase Conference Papers).