Unassisted photoelectrochemical water splitting beyond 5.7% solar-to-hydrogen conversion efficiency by a wireless monolithic photoanode/dye-sensitised solar cell tandem device

Xinjian Shi, Kan Zhang, Kahee Shin, Ming Ma, Jeong Kwon, In Taek Choi, Jung Kyu Kim, Hwan Kyu Kim, Dong Hwan Wang, Jong Hyeok Park

Research output: Contribution to journalArticle

71 Citations (Scopus)

Abstract

Achieving the spontaneous evolution of hydrogen from photoelectrochemical (PEC) cells in water using solar light is a desirable but difficult goal. Here, we report a highly efficient wireless monolithic tandem device composed of bipolar highly transparent BiVO4-sensitised mesoporous WO3 films/Pt and a porphyrin-dye-based photoelectrode achieving 5.7% without any external bias. A sandwich infiltration process was used to produce a thin BiVO4 layer coated onto mesoporous WO3 films while preserving high transparency, enabling high photonic flux into the second dye-sensitised photoanode. In addition, the porphyrin-dye-sensitised photoanode with a cobalt electrolyte generated sufficient bias, realising highly efficient unassisted solar water splitting in the tandem cells. By combining the highly transparent BiVO4-sensitised mesoporous WO3 films with the state-of-the-art water oxidation catalyst and a single dye-sensitised solar cell with a high open circuit potential in a monolithic tandem configuration, an extraordinarily high solar-to-hydrogen (STH) conversion efficiency with spontaneous hydrogen evolution was obtained.

Original languageEnglish
Pages (from-to)182-191
Number of pages10
JournalNano Energy
Volume13
DOIs
Publication statusPublished - 2015 Apr 1

Fingerprint

Conversion efficiency
Hydrogen
Coloring Agents
Dyes
Porphyrins
Water
Photoelectrochemical cells
Cobalt
Infiltration
Transparency
Photonics
Electrolytes
Fluxes
Oxidation
Catalysts
Networks (circuits)
bismuth vanadium tetraoxide
Dye-sensitized solar cells

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)
  • Electrical and Electronic Engineering

Cite this

Shi, Xinjian ; Zhang, Kan ; Shin, Kahee ; Ma, Ming ; Kwon, Jeong ; Choi, In Taek ; Kim, Jung Kyu ; Kim, Hwan Kyu ; Wang, Dong Hwan ; Park, Jong Hyeok. / Unassisted photoelectrochemical water splitting beyond 5.7% solar-to-hydrogen conversion efficiency by a wireless monolithic photoanode/dye-sensitised solar cell tandem device. In: Nano Energy. 2015 ; Vol. 13. pp. 182-191.
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Unassisted photoelectrochemical water splitting beyond 5.7% solar-to-hydrogen conversion efficiency by a wireless monolithic photoanode/dye-sensitised solar cell tandem device. / Shi, Xinjian; Zhang, Kan; Shin, Kahee; Ma, Ming; Kwon, Jeong; Choi, In Taek; Kim, Jung Kyu; Kim, Hwan Kyu; Wang, Dong Hwan; Park, Jong Hyeok.

In: Nano Energy, Vol. 13, 01.04.2015, p. 182-191.

Research output: Contribution to journalArticle

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