Understanding negative thermal expansion and 'trap door' cation relocations in zeolite rho

B. A. Reisner, Y. Lee, J. C. Hanson, G. A. Jones, J. B. Parise, D. R. Corbin, B. H. Toby, A. Freitag, J. Z. Larese, V. Kahlenberg

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Abstract

In situ time-resolved synchrotron X-ray and neutron powder diffraction studies indicate that the negative thermal expansion and 'trap door' cation relocations observed in zeolite rho result from water-mediated chemical changes that occur during dehydration.

Original languageEnglish
Pages (from-to)2221-2222
Number of pages2
JournalChemical Communications
Issue number22
DOIs
Publication statusPublished - 2000 Nov 21

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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    Reisner, B. A., Lee, Y., Hanson, J. C., Jones, G. A., Parise, J. B., Corbin, D. R., Toby, B. H., Freitag, A., Larese, J. Z., & Kahlenberg, V. (2000). Understanding negative thermal expansion and 'trap door' cation relocations in zeolite rho. Chemical Communications, (22), 2221-2222. https://doi.org/10.1039/b006929i