Use of amphiphilic graft copolymer as dispersant for carbon nanotubes

Harim Jeon, Sung Hoon Ahn, Won Seok Chi, Jong Hak Kim

Research output: Contribution to journalArticle

Abstract

Carbon nanotubes (CNTs) draw attention as promising materials due to their excellent electrical and mechanical properties. However, the intrinsic strong interaction between CNTs presents a challenge to their use in various applications. Here, we present a facile method to disperse single-walled carbon nanotubes (SWCNTs) in a polar solution using a graft copolymer, poly (vinyl chloride) graft -poly (oxyethylene methacrylate), PVC-.g-POEM. The graft copolymer was synthesized via atom transfer radical polymerization (ATRP), as confirmed by gel permeation chromatography (GPC) and 1H NMR spectroscopy. The SWCNTs were uniformly dispersed in a polar solvent such as dimethylsiloxane (DMSO) using PVC-g-POEM as a dispersant, due to interaction between CNT and the graft copolymer, as revealed by transmission electron microscopy (TEM) analysis. Upon removal of the solvent, free standing nanocomposite films with good homogeneity were obtained.

Original languageEnglish
Pages (from-to)615-618
Number of pages4
JournalPolymer (Korea)
Volume35
Issue number6
Publication statusPublished - 2011 Nov 1

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Carbon Nanotubes
Graft copolymers
Carbon nanotubes
Single-walled carbon nanotubes (SWCN)
Polyvinyl chlorides
Dimethylpolysiloxanes
Vinyl Chloride
Nanocomposite films
Methacrylates
Atom transfer radical polymerization
Gel permeation chromatography
Polyvinyl Chloride
Grafts
Nuclear magnetic resonance spectroscopy
Electric properties
Transmission electron microscopy
Mechanical properties

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Polymers and Plastics
  • Materials Chemistry

Cite this

Jeon, Harim ; Ahn, Sung Hoon ; Chi, Won Seok ; Kim, Jong Hak. / Use of amphiphilic graft copolymer as dispersant for carbon nanotubes. In: Polymer (Korea). 2011 ; Vol. 35, No. 6. pp. 615-618.
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Jeon, H, Ahn, SH, Chi, WS & Kim, JH 2011, 'Use of amphiphilic graft copolymer as dispersant for carbon nanotubes', Polymer (Korea), vol. 35, no. 6, pp. 615-618.

Use of amphiphilic graft copolymer as dispersant for carbon nanotubes. / Jeon, Harim; Ahn, Sung Hoon; Chi, Won Seok; Kim, Jong Hak.

In: Polymer (Korea), Vol. 35, No. 6, 01.11.2011, p. 615-618.

Research output: Contribution to journalArticle

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