Vacuum-integrated electrospray deposition for highly reliable polymer thin film

Soohyung Park, Younjoo Lee, Yeonjin Yi

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Vacuum electrospray deposition (ESD) equipment was designed to prepare polymer thin films. The polymer solution can be injected directly into vacuum system through multi-stage pumping line, so that the solvent residues and ambient contaminants are highly reduced. To test the performance of ESD system, we fabricated organic photovoltaic cells (OPVCs) by injecting polymer solution directly onto the substrate inside a high vacuum chamber. The OPVC fabricated has the structure of AlP3HT:PCBMPEDOT:PSSITO and was optimized by varying the speed of solution injection and concentration of the solution. The power conversion efficiency (PCE) of the optimized OPVC is 3.14% under AM 1.5G irradiation without any buffer layer at the cathode side. To test the advantages of the vacuum ESD, we exposed the device to atmosphere between the deposition steps of the active layer and cathode. This showed that the PCE of the vacuum processed device is 24 higher than that of the air exposed device and confirms the advantages of the vacuum prepared polymer film for high performance devices.

Original languageEnglish
Article number105106
JournalReview of Scientific Instruments
Volume83
Issue number10
DOIs
Publication statusPublished - 2012 Oct 1

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Polymer films
photovoltaic cells
Vacuum
Thin films
vacuum
vacuum deposition
Photovoltaic cells
polymers
thin films
cathodes
Polymer solutions
Conversion efficiency
vacuum systems
Cathodes
vacuum chambers
high vacuum
contaminants
pumping
buffers
Buffer layers

All Science Journal Classification (ASJC) codes

  • Instrumentation

Cite this

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Vacuum-integrated electrospray deposition for highly reliable polymer thin film. / Park, Soohyung; Lee, Younjoo; Yi, Yeonjin.

In: Review of Scientific Instruments, Vol. 83, No. 10, 105106, 01.10.2012.

Research output: Contribution to journalArticle

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