Vapor-liquid equilibria of 2-butanol + aromatic hydrocarbons at 308.15 K

Sanjeev Maken, Umesh Bhardwaj, Bal Raj Deshwal, Krishan Chander Singh, Jin Won Park, Sang Do Han

Research output: Contribution to journalArticle

Abstract

Vapor-liquid equilibria (VLE) data of 2-butanol + benzene or toluene or o- or m- or p-xylene measured by static method at 308.15 ± 0.01 K over the entire composition range are reported. The excess molar Gibbs free energies of mixing (GF) for these binary systems have been calculated from total vapor pressure data using Barker's method. The GE for these binary systems are also analyzed in terms of the Mecke Kempter type of association model with a Flory contribution term using two interaction parameters and it has been found that this model describes well the GE values of binary systems benzene or toluene.

Original languageEnglish
Pages (from-to)447-456
Number of pages10
JournalPhysics and Chemistry of Liquids
Volume42
Issue number5
DOIs
Publication statusPublished - 2004 Oct

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Materials Chemistry

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