Versatile double hydrophilic block copolymer

Dual role as synthetic nanoreactor and ionic and electronic conduction layer for ruthenium oxide nanoparticle supercapacitors

Eunyong Seo, Taemin Lee, Kyu Tae Lee, Hyun Kon Song, Byeong Su Kim

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

The facile synthetic approach to ruthenium oxide nanoparticles using double hydrophilic block copolymers (DHBCs) and their application toward the supercapacitor are presented. Nanostructured hydrous ruthenium oxide (RuO 2) nanoparticles are synthesized using a double hydrophilic block copolymer of poly(ethylene oxide)-block-poly(acrylic acid) (PEO-b-PAA) as a template, forming a micelle upon addition of the ruthenium precursor, which then transformed into RuO 2 nanoparticles of controlled dimension with reducing agents. The synthesized hydrous RuO 2·xH 2O nanoparticles are very stable for several months without any noticeable aggregates. Furthermore, we have demonstrated their utility in application as supercapacitors. Through annealing at 400 °C, we found that the crystallinity of RuO 2 nanoparticles increases considerably with a simultaneous transformation of the surrounding double hydrophilic block copolymer into ionic and electronic conducting buffer layers atop RuO 2 nanoparticles, which contribute to the significant enhancement of the overall specific capacitance from 106 to 962 F g -1 at 10 mV s -1. The RuO 2 nanoparticles annealed at 400 °C also exhibit a superior retention of capacitance over 1000 cycles at very high charge-discharge rates at 20 A g -1. We envision that the double hydrophilic block copolymer will provide a facile and general tool in creating functional nanostructures with controlled dimensions that are useful for various applications.

Original languageEnglish
Pages (from-to)11598-11604
Number of pages7
JournalJournal of Materials Chemistry
Volume22
Issue number23
DOIs
Publication statusPublished - 2012 Jun 21

Fingerprint

Nanoreactors
Ruthenium
Oxides
Block copolymers
Nanoparticles
carbopol 940
Capacitance
Reducing Agents
Micelles
Reducing agents
Buffer layers
Polyethylene oxides
Supercapacitor
Acrylics
Nanostructures
Annealing
Acids

All Science Journal Classification (ASJC) codes

  • Materials Chemistry
  • Chemistry(all)

Cite this

@article{bdf77457339a4b2db22cbbaecb895bca,
title = "Versatile double hydrophilic block copolymer: Dual role as synthetic nanoreactor and ionic and electronic conduction layer for ruthenium oxide nanoparticle supercapacitors",
abstract = "The facile synthetic approach to ruthenium oxide nanoparticles using double hydrophilic block copolymers (DHBCs) and their application toward the supercapacitor are presented. Nanostructured hydrous ruthenium oxide (RuO 2) nanoparticles are synthesized using a double hydrophilic block copolymer of poly(ethylene oxide)-block-poly(acrylic acid) (PEO-b-PAA) as a template, forming a micelle upon addition of the ruthenium precursor, which then transformed into RuO 2 nanoparticles of controlled dimension with reducing agents. The synthesized hydrous RuO 2·xH 2O nanoparticles are very stable for several months without any noticeable aggregates. Furthermore, we have demonstrated their utility in application as supercapacitors. Through annealing at 400 °C, we found that the crystallinity of RuO 2 nanoparticles increases considerably with a simultaneous transformation of the surrounding double hydrophilic block copolymer into ionic and electronic conducting buffer layers atop RuO 2 nanoparticles, which contribute to the significant enhancement of the overall specific capacitance from 106 to 962 F g -1 at 10 mV s -1. The RuO 2 nanoparticles annealed at 400 °C also exhibit a superior retention of capacitance over 1000 cycles at very high charge-discharge rates at 20 A g -1. We envision that the double hydrophilic block copolymer will provide a facile and general tool in creating functional nanostructures with controlled dimensions that are useful for various applications.",
author = "Eunyong Seo and Taemin Lee and Lee, {Kyu Tae} and Song, {Hyun Kon} and Kim, {Byeong Su}",
year = "2012",
month = "6",
day = "21",
doi = "10.1039/c2jm30738c",
language = "English",
volume = "22",
pages = "11598--11604",
journal = "Journal of Materials Chemistry",
issn = "0959-9428",
publisher = "Royal Society of Chemistry",
number = "23",

}

Versatile double hydrophilic block copolymer : Dual role as synthetic nanoreactor and ionic and electronic conduction layer for ruthenium oxide nanoparticle supercapacitors. / Seo, Eunyong; Lee, Taemin; Lee, Kyu Tae; Song, Hyun Kon; Kim, Byeong Su.

In: Journal of Materials Chemistry, Vol. 22, No. 23, 21.06.2012, p. 11598-11604.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Versatile double hydrophilic block copolymer

T2 - Dual role as synthetic nanoreactor and ionic and electronic conduction layer for ruthenium oxide nanoparticle supercapacitors

AU - Seo, Eunyong

AU - Lee, Taemin

AU - Lee, Kyu Tae

AU - Song, Hyun Kon

AU - Kim, Byeong Su

PY - 2012/6/21

Y1 - 2012/6/21

N2 - The facile synthetic approach to ruthenium oxide nanoparticles using double hydrophilic block copolymers (DHBCs) and their application toward the supercapacitor are presented. Nanostructured hydrous ruthenium oxide (RuO 2) nanoparticles are synthesized using a double hydrophilic block copolymer of poly(ethylene oxide)-block-poly(acrylic acid) (PEO-b-PAA) as a template, forming a micelle upon addition of the ruthenium precursor, which then transformed into RuO 2 nanoparticles of controlled dimension with reducing agents. The synthesized hydrous RuO 2·xH 2O nanoparticles are very stable for several months without any noticeable aggregates. Furthermore, we have demonstrated their utility in application as supercapacitors. Through annealing at 400 °C, we found that the crystallinity of RuO 2 nanoparticles increases considerably with a simultaneous transformation of the surrounding double hydrophilic block copolymer into ionic and electronic conducting buffer layers atop RuO 2 nanoparticles, which contribute to the significant enhancement of the overall specific capacitance from 106 to 962 F g -1 at 10 mV s -1. The RuO 2 nanoparticles annealed at 400 °C also exhibit a superior retention of capacitance over 1000 cycles at very high charge-discharge rates at 20 A g -1. We envision that the double hydrophilic block copolymer will provide a facile and general tool in creating functional nanostructures with controlled dimensions that are useful for various applications.

AB - The facile synthetic approach to ruthenium oxide nanoparticles using double hydrophilic block copolymers (DHBCs) and their application toward the supercapacitor are presented. Nanostructured hydrous ruthenium oxide (RuO 2) nanoparticles are synthesized using a double hydrophilic block copolymer of poly(ethylene oxide)-block-poly(acrylic acid) (PEO-b-PAA) as a template, forming a micelle upon addition of the ruthenium precursor, which then transformed into RuO 2 nanoparticles of controlled dimension with reducing agents. The synthesized hydrous RuO 2·xH 2O nanoparticles are very stable for several months without any noticeable aggregates. Furthermore, we have demonstrated their utility in application as supercapacitors. Through annealing at 400 °C, we found that the crystallinity of RuO 2 nanoparticles increases considerably with a simultaneous transformation of the surrounding double hydrophilic block copolymer into ionic and electronic conducting buffer layers atop RuO 2 nanoparticles, which contribute to the significant enhancement of the overall specific capacitance from 106 to 962 F g -1 at 10 mV s -1. The RuO 2 nanoparticles annealed at 400 °C also exhibit a superior retention of capacitance over 1000 cycles at very high charge-discharge rates at 20 A g -1. We envision that the double hydrophilic block copolymer will provide a facile and general tool in creating functional nanostructures with controlled dimensions that are useful for various applications.

UR - http://www.scopus.com/inward/record.url?scp=84862225318&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84862225318&partnerID=8YFLogxK

U2 - 10.1039/c2jm30738c

DO - 10.1039/c2jm30738c

M3 - Article

VL - 22

SP - 11598

EP - 11604

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

SN - 0959-9428

IS - 23

ER -