Versatile Solution-Processed Organic–Inorganic Hybrid Superlattices for Ultraflexible and Transparent High-Performance Optoelectronic Devices

Minh Nhut Le, Kang Jun Baeg, Kyung Tae Kim, Seung Han Kang, Byung Doo Choi, Chan Yong Park, Seong Pil Jeon, Sol Lee, Jeong Wan Jo, Seonhyoung Kim, Jun Gu Park, Dongil Ho, Jongin Hong, Miso Kim, Han Ki Kim, Choongik Kim, Kwanpyo Kim, Yong Hoon Kim, Sung Kyu Park, Myung Gil Kim

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)


Crystalline or amorphous metal oxides are widely used in various optoelectronic devices as key components, such as transparent conductive electrodes, dielectrics or semiconducting active layers for thin-film transistor (TFT) backplanes in large-area displays, photovoltaics, and light-emitting diodes. Although crystalline inorganic materials demonstrate outstanding optoelectronic performance, owing to their wide bandgaps, large conductivities, and high carrier mobilities, their inherent brittleness makes them vulnerable to mechanical stress, thereby limiting the use of metal-oxide films in emerging flexible electronic applications. In this study, stress-diffusive organic–inorganic hybrid superlattice nanostructures are developed to overcome the mechanical limitation of crystalline oxides and to provide high mechanical stability to metal-oxide semiconductors. In particular, hybrid transparent superlattice electrodes based on crystalline indium–tin oxide exhibit high electrical conductivities of up to 555 S cm–1 (resistance variation < 3%) and effectively reduce the mechanical stress on the inorganic layer (up to 10 000 bending cycles with a radius of 1 mm). Furthermore, to ensure the viability of the hybrid superlattice flexible electronics, all solution-processed superlattice crystalline indium–gallium-oxide TFTs are implemented on a thin (≈5 µm) polyimide substrate, providing highly robust and excellent electrical performance (average mobility of 7.6 cm2 V–1 s–1).

Original languageEnglish
Article number2103285
JournalAdvanced Functional Materials
Issue number29
Publication statusPublished - 2021 Jul 16

Bibliographical note

Funding Information:
M.N.L. and K.‐J.B. contributed equally to this work. This study was supported in part by the National Research Foundation of Korea (NRF) grant funded by the Korea government (Grant Nos. 2020R1A2C4001617 and 2019R1F1A1059604) and the Technology Innovation Program (Program Nos. 20010082 and 20012617) by the Ministry of Trade, Industry & Energy (MOTIE, Korea).

Publisher Copyright:
© 2021 Wiley-VCH GmbH.

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics


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