Violet and UV luminescence emitted from ZnO thin films grown on sapphire by pulsed laser deposition

B. J. Jin, Seongil Im, S. Y. Lee

Research output: Contribution to journalArticle

467 Citations (Scopus)

Abstract

Visible violet photoluminescence (PL) has been achieved at room temperature (RT) from ZnO films grown on sapphire (001) substrate by pulsed laser deposition (PLD). Substrate temperatures of 200, 300, and 400°C have been used in an oxygen pressure of 1 mTorr during the PLD. As the oxygen pressure for the thin film deposition increases over 20 mTorr at a substrate temperature of 400°C, the violet luminescence vanishes. Instead ultra-violet (UV) and green-yellow luminescence appear. The most intense UV and green-yellow luminescence is obtained from a sample grown in an oxygen pressure of 200 mTorr at 400°C. It is concluded that the intensity of the UV luminescence strongly depends on the stoichiometry of the film as well as the crystalline quality, while the violet PL is due to a defect level in the grain boundaries of the ZnOx crystals.

Original languageEnglish
Pages (from-to)107-110
Number of pages4
JournalThin Solid Films
Volume366
Issue number1-2
DOIs
Publication statusPublished - 2000 May 1

Fingerprint

Aluminum Oxide
Pulsed laser deposition
Sapphire
pulsed laser deposition
Luminescence
sapphire
luminescence
Thin films
Oxygen
thin films
Photoluminescence
oxygen
Substrates
photoluminescence
Stoichiometry
Temperature
stoichiometry
Grain boundaries
grain boundaries
Crystalline materials

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

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title = "Violet and UV luminescence emitted from ZnO thin films grown on sapphire by pulsed laser deposition",
abstract = "Visible violet photoluminescence (PL) has been achieved at room temperature (RT) from ZnO films grown on sapphire (001) substrate by pulsed laser deposition (PLD). Substrate temperatures of 200, 300, and 400°C have been used in an oxygen pressure of 1 mTorr during the PLD. As the oxygen pressure for the thin film deposition increases over 20 mTorr at a substrate temperature of 400°C, the violet luminescence vanishes. Instead ultra-violet (UV) and green-yellow luminescence appear. The most intense UV and green-yellow luminescence is obtained from a sample grown in an oxygen pressure of 200 mTorr at 400°C. It is concluded that the intensity of the UV luminescence strongly depends on the stoichiometry of the film as well as the crystalline quality, while the violet PL is due to a defect level in the grain boundaries of the ZnOx crystals.",
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Violet and UV luminescence emitted from ZnO thin films grown on sapphire by pulsed laser deposition. / Jin, B. J.; Im, Seongil; Lee, S. Y.

In: Thin Solid Films, Vol. 366, No. 1-2, 01.05.2000, p. 107-110.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Violet and UV luminescence emitted from ZnO thin films grown on sapphire by pulsed laser deposition

AU - Jin, B. J.

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AU - Lee, S. Y.

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N2 - Visible violet photoluminescence (PL) has been achieved at room temperature (RT) from ZnO films grown on sapphire (001) substrate by pulsed laser deposition (PLD). Substrate temperatures of 200, 300, and 400°C have been used in an oxygen pressure of 1 mTorr during the PLD. As the oxygen pressure for the thin film deposition increases over 20 mTorr at a substrate temperature of 400°C, the violet luminescence vanishes. Instead ultra-violet (UV) and green-yellow luminescence appear. The most intense UV and green-yellow luminescence is obtained from a sample grown in an oxygen pressure of 200 mTorr at 400°C. It is concluded that the intensity of the UV luminescence strongly depends on the stoichiometry of the film as well as the crystalline quality, while the violet PL is due to a defect level in the grain boundaries of the ZnOx crystals.

AB - Visible violet photoluminescence (PL) has been achieved at room temperature (RT) from ZnO films grown on sapphire (001) substrate by pulsed laser deposition (PLD). Substrate temperatures of 200, 300, and 400°C have been used in an oxygen pressure of 1 mTorr during the PLD. As the oxygen pressure for the thin film deposition increases over 20 mTorr at a substrate temperature of 400°C, the violet luminescence vanishes. Instead ultra-violet (UV) and green-yellow luminescence appear. The most intense UV and green-yellow luminescence is obtained from a sample grown in an oxygen pressure of 200 mTorr at 400°C. It is concluded that the intensity of the UV luminescence strongly depends on the stoichiometry of the film as well as the crystalline quality, while the violet PL is due to a defect level in the grain boundaries of the ZnOx crystals.

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