Volumetric properties of 1,3-dioxolane + toluene + o- or p-xylene ternary mixtures at 25.00°c and atmospheric pressure

Satish Kumar, V. K. Sharma, il Moon

Research output: Contribution to journalArticle

Abstract

Excess molar volumes, V123E V 123 E, of 1, 3-dioxolane (1) + toluene (2) + o- or p-xylene (3) ternary mixtures have been determined dilatometrically over the entire composition range at 298.15 K. For thermodynamic consistency the experimental values were fitted to Redlich-Kister Equation. The V123E V 123 E values of 1, 3-dioxolane (1) + toluene (2) + o- or p-xylene (3) ternary mixtures have been found to be negative over the whole composition range. It has been observed that V 123E V 123 E values calculated by graph theory are of the same sign and magnitude with respect to their experimental values.

Original languageEnglish
Pages (from-to)936-944
Number of pages9
JournalJournal of Solution Chemistry
Volume42
Issue number5
DOIs
Publication statusPublished - 2013 Jun 1

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Atmospheric Pressure
Toluene
xylene
Atmospheric pressure
toluene
atmospheric pressure
graph theory
Graph theory
Chemical analysis
Thermodynamics
Density (specific gravity)
thermodynamics
4-xylene
2-xylene
formal glycol

All Science Journal Classification (ASJC) codes

  • Biophysics
  • Biochemistry
  • Molecular Biology
  • Physical and Theoretical Chemistry

Cite this

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title = "Volumetric properties of 1,3-dioxolane + toluene + o- or p-xylene ternary mixtures at 25.00°c and atmospheric pressure",
abstract = "Excess molar volumes, V123E V 123 E, of 1, 3-dioxolane (1) + toluene (2) + o- or p-xylene (3) ternary mixtures have been determined dilatometrically over the entire composition range at 298.15 K. For thermodynamic consistency the experimental values were fitted to Redlich-Kister Equation. The V123E V 123 E values of 1, 3-dioxolane (1) + toluene (2) + o- or p-xylene (3) ternary mixtures have been found to be negative over the whole composition range. It has been observed that V 123E V 123 E values calculated by graph theory are of the same sign and magnitude with respect to their experimental values.",
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Volumetric properties of 1,3-dioxolane + toluene + o- or p-xylene ternary mixtures at 25.00°c and atmospheric pressure. / Kumar, Satish; Sharma, V. K.; Moon, il.

In: Journal of Solution Chemistry, Vol. 42, No. 5, 01.06.2013, p. 936-944.

Research output: Contribution to journalArticle

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