Volumetric properties of 1,3-dioxolane + toluene + o- or p-xylene ternary mixtures at 25.00°c and atmospheric pressure

Satish Kumar; V. K. Sharma; Il Moon

doi:10.1007/s10953-013-0017-7

Volumetric properties of 1,3-dioxolane + toluene + o- or p-xylene ternary mixtures at 25.00°c and atmospheric pressure

Satish Kumar, V. K. Sharma, Il Moon

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Excess molar volumes, V₁₂₃^E V 123 E, of 1, 3-dioxolane (1) + toluene (2) + o- or p-xylene (3) ternary mixtures have been determined dilatometrically over the entire composition range at 298.15 K. For thermodynamic consistency the experimental values were fitted to Redlich-Kister Equation. The V₁₂₃^E V 123 E values of 1, 3-dioxolane (1) + toluene (2) + o- or p-xylene (3) ternary mixtures have been found to be negative over the whole composition range. It has been observed that V ₁₂₃^E V 123 E values calculated by graph theory are of the same sign and magnitude with respect to their experimental values.

Original language	English
Pages (from-to)	936-944
Number of pages	9
Journal	Journal of Solution Chemistry
Volume	42
Issue number	5
DOIs	https://doi.org/10.1007/s10953-013-0017-7
Publication status	Published - 2013 Jun

Bibliographical note

Funding Information:
Acknowledgments This study was supported by the Ministry of Education (MOE) of Korea through its BK21 Program and GAS plant R&D Centre funded by the Ministry of Land, Transportation and Maritime Affairs (MLTM) of the Korean Government.

All Science Journal Classification (ASJC) codes

Biophysics
Biochemistry
Molecular Biology
Physical and Theoretical Chemistry

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title = "Volumetric properties of 1,3-dioxolane + toluene + o- or p-xylene ternary mixtures at 25.00°c and atmospheric pressure",

abstract = "Excess molar volumes, V123E V 123 E, of 1, 3-dioxolane (1) + toluene (2) + o- or p-xylene (3) ternary mixtures have been determined dilatometrically over the entire composition range at 298.15 K. For thermodynamic consistency the experimental values were fitted to Redlich-Kister Equation. The V123E V 123 E values of 1, 3-dioxolane (1) + toluene (2) + o- or p-xylene (3) ternary mixtures have been found to be negative over the whole composition range. It has been observed that V 123E V 123 E values calculated by graph theory are of the same sign and magnitude with respect to their experimental values.",

author = "Satish Kumar and Sharma, {V. K.} and Il Moon",

note = "Funding Information: Acknowledgments This study was supported by the Ministry of Education (MOE) of Korea through its BK21 Program and GAS plant R&D Centre funded by the Ministry of Land, Transportation and Maritime Affairs (MLTM) of the Korean Government.",

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AU - Sharma, V. K.

AU - Moon, Il

N1 - Funding Information: Acknowledgments This study was supported by the Ministry of Education (MOE) of Korea through its BK21 Program and GAS plant R&D Centre funded by the Ministry of Land, Transportation and Maritime Affairs (MLTM) of the Korean Government.

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AB - Excess molar volumes, V123E V 123 E, of 1, 3-dioxolane (1) + toluene (2) + o- or p-xylene (3) ternary mixtures have been determined dilatometrically over the entire composition range at 298.15 K. For thermodynamic consistency the experimental values were fitted to Redlich-Kister Equation. The V123E V 123 E values of 1, 3-dioxolane (1) + toluene (2) + o- or p-xylene (3) ternary mixtures have been found to be negative over the whole composition range. It has been observed that V 123E V 123 E values calculated by graph theory are of the same sign and magnitude with respect to their experimental values.

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Volumetric properties of 1,3-dioxolane + toluene + o- or p-xylene ternary mixtures at 25.00°c and atmospheric pressure

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

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