Abstract
Diastereomeric disiloxane-1,3-diols, 1, with two asymmetric silicon centers and intramolecular coordination arms were synthesized and separated manually. They show distinguishing structural features such as a linear or bent Si-O-Si skeleton, a short Si-O bond length, and strong intramolecular hydrogen bonding. A trace of water induced the diastreomeric isomerization of 1 under noncatalytic conditions, while the anhydrous disiloxane-1,3-diols were stereochemically stable.
| Original language | English |
|---|---|
| Pages (from-to) | 4297-4299 |
| Number of pages | 3 |
| Journal | Organometallics |
| Volume | 21 |
| Issue number | 21 |
| DOIs | |
| Publication status | Published - 2002 Oct 14 |
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
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Lee, M. E., Cho, H. M., Kang, D. J., Lee, J. S., & Kim, J. H. (2002). Water-induced diastereomeric isomerization of novel disiloxane-1,3-diols separated manually. Organometallics, 21(21), 4297-4299. https://doi.org/10.1021/om020427+