Abstract
Diastereomeric disiloxane-1,3-diols, 1, with two asymmetric silicon centers and intramolecular coordination arms were synthesized and separated manually. They show distinguishing structural features such as a linear or bent Si-O-Si skeleton, a short Si-O bond length, and strong intramolecular hydrogen bonding. A trace of water induced the diastreomeric isomerization of 1 under noncatalytic conditions, while the anhydrous disiloxane-1,3-diols were stereochemically stable.
| Original language | English |
|---|---|
| Pages (from-to) | 4297-4299 |
| Number of pages | 3 |
| Journal | Organometallics |
| Volume | 21 |
| Issue number | 21 |
| DOIs | |
| Publication status | Published - 2002 Oct 14 |
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All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
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Water-induced diastereomeric isomerization of novel disiloxane-1,3-diols separated manually. / Lee, Myong Euy; Cho, Hyeon Mo; Kang, Doo Jin; Lee, Ji Soo; Kim, Jung Hoon.
In: Organometallics, Vol. 21, No. 21, 14.10.2002, p. 4297-4299.Research output: Contribution to journal › Article
TY - JOUR
T1 - Water-induced diastereomeric isomerization of novel disiloxane-1,3-diols separated manually
AU - Lee, Myong Euy
AU - Cho, Hyeon Mo
AU - Kang, Doo Jin
AU - Lee, Ji Soo
AU - Kim, Jung Hoon
PY - 2002/10/14
Y1 - 2002/10/14
N2 - Diastereomeric disiloxane-1,3-diols, 1, with two asymmetric silicon centers and intramolecular coordination arms were synthesized and separated manually. They show distinguishing structural features such as a linear or bent Si-O-Si skeleton, a short Si-O bond length, and strong intramolecular hydrogen bonding. A trace of water induced the diastreomeric isomerization of 1 under noncatalytic conditions, while the anhydrous disiloxane-1,3-diols were stereochemically stable.
AB - Diastereomeric disiloxane-1,3-diols, 1, with two asymmetric silicon centers and intramolecular coordination arms were synthesized and separated manually. They show distinguishing structural features such as a linear or bent Si-O-Si skeleton, a short Si-O bond length, and strong intramolecular hydrogen bonding. A trace of water induced the diastreomeric isomerization of 1 under noncatalytic conditions, while the anhydrous disiloxane-1,3-diols were stereochemically stable.
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U2 - 10.1021/om020427+
DO - 10.1021/om020427+
M3 - Article
AN - SCOPUS:0037662018
VL - 21
SP - 4297
EP - 4299
JO - Organometallics
JF - Organometallics
SN - 0276-7333
IS - 21
ER -