Water-induced diastereomeric isomerization of novel disiloxane-1,3-diols separated manually

Myong Euy Lee, Hyeon Mo Cho, Doo Jin Kang, Ji Soo Lee, Jung Hoon Kim

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Diastereomeric disiloxane-1,3-diols, 1, with two asymmetric silicon centers and intramolecular coordination arms were synthesized and separated manually. They show distinguishing structural features such as a linear or bent Si-O-Si skeleton, a short Si-O bond length, and strong intramolecular hydrogen bonding. A trace of water induced the diastreomeric isomerization of 1 under noncatalytic conditions, while the anhydrous disiloxane-1,3-diols were stereochemically stable.

Original languageEnglish
Pages (from-to)4297-4299
Number of pages3
JournalOrganometallics
Volume21
Issue number21
DOIs
Publication statusPublished - 2002 Oct 14

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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