Abstract
Diastereomeric disiloxane-1,3-diols, 1, with two asymmetric silicon centers and intramolecular coordination arms were synthesized and separated manually. They show distinguishing structural features such as a linear or bent Si-O-Si skeleton, a short Si-O bond length, and strong intramolecular hydrogen bonding. A trace of water induced the diastreomeric isomerization of 1 under noncatalytic conditions, while the anhydrous disiloxane-1,3-diols were stereochemically stable.
Original language | English |
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Pages (from-to) | 4297-4299 |
Number of pages | 3 |
Journal | Organometallics |
Volume | 21 |
Issue number | 21 |
DOIs | |
Publication status | Published - 2002 Oct 14 |
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry