X-ray structure and properties of a cyclo[6]pyrrole[3]thiophene

Thanh Tuan Bui, Aude Escande, Christian Philouze, Gianluca Cioci, Sudip Ghosh, Eric Saint-Aman, Jong Min Lim, Jean Claude Moutet, Jonathan L. Sessler, Dongho Kim, Christophe Bucher

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

A new member of the cyclo[n]pyrrole class of expanded porphyrins was prepared from the corresponding thiophene-containing terpyrrole precursor through use of a mild electrochemical oxidative procedure. The isolated macrocycle, featuring nine heterocyclic subunits directly connected through their α,α′-positions, is the largest cyclo[n]pyrrole derivative reported to date. The structure obtained via synchrotron radiation-based studies revealed a dimeric arrangement involving individual macrocyclic subunits.

Original languageEnglish
Pages (from-to)27-35
Number of pages9
JournalJournal of Porphyrins and Phthalocyanines
Volume17
Issue number1-2
DOIs
Publication statusPublished - 2013 Jan 1

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Thiophenes
Pyrroles
X rays
Porphyrins
Synchrotron radiation
Derivatives

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Bui, T. T., Escande, A., Philouze, C., Cioci, G., Ghosh, S., Saint-Aman, E., ... Bucher, C. (2013). X-ray structure and properties of a cyclo[6]pyrrole[3]thiophene. Journal of Porphyrins and Phthalocyanines, 17(1-2), 27-35. https://doi.org/10.1142/S1088424612501325
Bui, Thanh Tuan ; Escande, Aude ; Philouze, Christian ; Cioci, Gianluca ; Ghosh, Sudip ; Saint-Aman, Eric ; Lim, Jong Min ; Moutet, Jean Claude ; Sessler, Jonathan L. ; Kim, Dongho ; Bucher, Christophe. / X-ray structure and properties of a cyclo[6]pyrrole[3]thiophene. In: Journal of Porphyrins and Phthalocyanines. 2013 ; Vol. 17, No. 1-2. pp. 27-35.
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Bui, TT, Escande, A, Philouze, C, Cioci, G, Ghosh, S, Saint-Aman, E, Lim, JM, Moutet, JC, Sessler, JL, Kim, D & Bucher, C 2013, 'X-ray structure and properties of a cyclo[6]pyrrole[3]thiophene', Journal of Porphyrins and Phthalocyanines, vol. 17, no. 1-2, pp. 27-35. https://doi.org/10.1142/S1088424612501325

X-ray structure and properties of a cyclo[6]pyrrole[3]thiophene. / Bui, Thanh Tuan; Escande, Aude; Philouze, Christian; Cioci, Gianluca; Ghosh, Sudip; Saint-Aman, Eric; Lim, Jong Min; Moutet, Jean Claude; Sessler, Jonathan L.; Kim, Dongho; Bucher, Christophe.

In: Journal of Porphyrins and Phthalocyanines, Vol. 17, No. 1-2, 01.01.2013, p. 27-35.

Research output: Contribution to journalArticle

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AU - Bui, Thanh Tuan

AU - Escande, Aude

AU - Philouze, Christian

AU - Cioci, Gianluca

AU - Ghosh, Sudip

AU - Saint-Aman, Eric

AU - Lim, Jong Min

AU - Moutet, Jean Claude

AU - Sessler, Jonathan L.

AU - Kim, Dongho

AU - Bucher, Christophe

PY - 2013/1/1

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Bui TT, Escande A, Philouze C, Cioci G, Ghosh S, Saint-Aman E et al. X-ray structure and properties of a cyclo[6]pyrrole[3]thiophene. Journal of Porphyrins and Phthalocyanines. 2013 Jan 1;17(1-2):27-35. https://doi.org/10.1142/S1088424612501325