ZnO:Ga-graded ITO electrodes to control interface between PCBM and ITO in planar perovskite solar cells

Hae Jun Seok, Azmat Ali, Jung Hwa Seo, Hyun Hwi Lee, Na Eun Jung, Yeonjin Yi, Han Ki Kim

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Ga-doped ZnO (GZO)-graded layer, facilitating electron extraction from electron transport layer, was integrated on the surface of transparent indium tin oxide (ITO) cathode by using graded sputtering technique to improve the performance of planar n-i-p perovskite solar cells (PSCs). The thickness of graded GZO layer was controlled to optimize GZO–indium tin oxide (ITO) combined electrode for planar n-i-p PSCs. At optimized graded thickness of 15 nm, the GZO–ITO combined electrode showed an optical transmittance of 95%, a resistivity of 2.3 × 10−4 Ohm cm, a sheet resistance of 15.6 Ohm/square, and work function of 4.23 eV, which is well matched with the 4.0-eV lowest unoccupied molecular orbital of [6,6]-phenyl-C61-butyric acid methyl ester. Owing to enhanced extraction of electron by the graded GZO, the n-i-p PSC with GZO–ITO combined electrode showed higher power conversion efficiency (PCE) of 9.67% than the PCE (5.25%) of PSC with only ITO electrode without GZO-graded layer. In addition, the GZO integrated-ITO electrode acts as transparent electrode and electron extraction layer simultaneously due to graded mixing of the GZO at the surface region of ITO electrode.

Original languageEnglish
Pages (from-to)389-400
Number of pages12
JournalScience and Technology of Advanced Materials
Volume20
Issue number1
DOIs
Publication statusPublished - 2019 Dec 31

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Tin oxides
Indium
Electrodes
Conversion efficiency
Electrons
Butyric acid
Sheet resistance
Opacity
Molecular orbitals
Perovskite solar cells
indium tin oxide
Sputtering
Esters
Cathodes

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Cite this

Seok, Hae Jun ; Ali, Azmat ; Seo, Jung Hwa ; Lee, Hyun Hwi ; Jung, Na Eun ; Yi, Yeonjin ; Kim, Han Ki. / ZnO:Ga-graded ITO electrodes to control interface between PCBM and ITO in planar perovskite solar cells. In: Science and Technology of Advanced Materials. 2019 ; Vol. 20, No. 1. pp. 389-400.
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abstract = "Ga-doped ZnO (GZO)-graded layer, facilitating electron extraction from electron transport layer, was integrated on the surface of transparent indium tin oxide (ITO) cathode by using graded sputtering technique to improve the performance of planar n-i-p perovskite solar cells (PSCs). The thickness of graded GZO layer was controlled to optimize GZO–indium tin oxide (ITO) combined electrode for planar n-i-p PSCs. At optimized graded thickness of 15 nm, the GZO–ITO combined electrode showed an optical transmittance of 95{\%}, a resistivity of 2.3 × 10−4 Ohm cm, a sheet resistance of 15.6 Ohm/square, and work function of 4.23 eV, which is well matched with the 4.0-eV lowest unoccupied molecular orbital of [6,6]-phenyl-C61-butyric acid methyl ester. Owing to enhanced extraction of electron by the graded GZO, the n-i-p PSC with GZO–ITO combined electrode showed higher power conversion efficiency (PCE) of 9.67{\%} than the PCE (5.25{\%}) of PSC with only ITO electrode without GZO-graded layer. In addition, the GZO integrated-ITO electrode acts as transparent electrode and electron extraction layer simultaneously due to graded mixing of the GZO at the surface region of ITO electrode.",
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ZnO:Ga-graded ITO electrodes to control interface between PCBM and ITO in planar perovskite solar cells. / Seok, Hae Jun; Ali, Azmat; Seo, Jung Hwa; Lee, Hyun Hwi; Jung, Na Eun; Yi, Yeonjin; Kim, Han Ki.

In: Science and Technology of Advanced Materials, Vol. 20, No. 1, 31.12.2019, p. 389-400.

Research output: Contribution to journalArticle

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T1 - ZnO:Ga-graded ITO electrodes to control interface between PCBM and ITO in planar perovskite solar cells

AU - Seok, Hae Jun

AU - Ali, Azmat

AU - Seo, Jung Hwa

AU - Lee, Hyun Hwi

AU - Jung, Na Eun

AU - Yi, Yeonjin

AU - Kim, Han Ki

PY - 2019/12/31

Y1 - 2019/12/31

N2 - Ga-doped ZnO (GZO)-graded layer, facilitating electron extraction from electron transport layer, was integrated on the surface of transparent indium tin oxide (ITO) cathode by using graded sputtering technique to improve the performance of planar n-i-p perovskite solar cells (PSCs). The thickness of graded GZO layer was controlled to optimize GZO–indium tin oxide (ITO) combined electrode for planar n-i-p PSCs. At optimized graded thickness of 15 nm, the GZO–ITO combined electrode showed an optical transmittance of 95%, a resistivity of 2.3 × 10−4 Ohm cm, a sheet resistance of 15.6 Ohm/square, and work function of 4.23 eV, which is well matched with the 4.0-eV lowest unoccupied molecular orbital of [6,6]-phenyl-C61-butyric acid methyl ester. Owing to enhanced extraction of electron by the graded GZO, the n-i-p PSC with GZO–ITO combined electrode showed higher power conversion efficiency (PCE) of 9.67% than the PCE (5.25%) of PSC with only ITO electrode without GZO-graded layer. In addition, the GZO integrated-ITO electrode acts as transparent electrode and electron extraction layer simultaneously due to graded mixing of the GZO at the surface region of ITO electrode.

AB - Ga-doped ZnO (GZO)-graded layer, facilitating electron extraction from electron transport layer, was integrated on the surface of transparent indium tin oxide (ITO) cathode by using graded sputtering technique to improve the performance of planar n-i-p perovskite solar cells (PSCs). The thickness of graded GZO layer was controlled to optimize GZO–indium tin oxide (ITO) combined electrode for planar n-i-p PSCs. At optimized graded thickness of 15 nm, the GZO–ITO combined electrode showed an optical transmittance of 95%, a resistivity of 2.3 × 10−4 Ohm cm, a sheet resistance of 15.6 Ohm/square, and work function of 4.23 eV, which is well matched with the 4.0-eV lowest unoccupied molecular orbital of [6,6]-phenyl-C61-butyric acid methyl ester. Owing to enhanced extraction of electron by the graded GZO, the n-i-p PSC with GZO–ITO combined electrode showed higher power conversion efficiency (PCE) of 9.67% than the PCE (5.25%) of PSC with only ITO electrode without GZO-graded layer. In addition, the GZO integrated-ITO electrode acts as transparent electrode and electron extraction layer simultaneously due to graded mixing of the GZO at the surface region of ITO electrode.

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